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KMID : 1059519890330010106
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Journal of the Korean Chemical Society
1989 Volume.33 No. 1 p.106 ~ p.112
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A Selective Oxidation of Tetraline by Chromium (Ⅵ) Compounds (Ⅰ)
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Bae Sun-Kun
Lee Sang-Bong
Park Dae-Chul
Lee Kyu-Wan
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Abstract
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Liquid phase oxidation of tetralin with clean air were carried out utilizing complexes composed of various heterocyclic base and CrO3 in N,N-dialkylamides. In the CrO3-N,N-dialkylacetamide complex catalyzed oxidations of tetralin at 90℃, the maximum conversion of tetralin to the products and selectivity of α-tetralone were 35.2% and 96.1%, respectively. Under this condition, however, negligible amount of α-tetralol was determined.
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KEYWORD
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